Product ID:MACS NON-CHLORINATED BRAKE CLEANER 4800
MSDS Date:02/03/1995
FSC:6850
NIIN:00N073627
MSDS Number: CCNZF

VALVOLINE CO

LEXINGTON, KY 40512
US

Emergency Phone: 800-274-5263

Info Phone: 606-357-7847

Cage: IO754

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 40%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 29%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM; 250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

VM & P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES)

CAS: 64742-89-8

Fraction By Weight: 22-32%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 0.0-9.0%

OSHA PEL 5000 PPM

ACGIH TLV: 5000 PPM; 30000 STEL

CONSULTATION FROM APPROP HLTH PROFESSIONALS

RTECS: 9999999ZZ

. OVEREXP TO MATL (OR COMPONENTS) HAS BEEN SUGGESTED

RTECS: 9999999ZZ

AGGRAVATE PRE-EXISTING DISORDERS OF THESE ORGANS IN

RTECS: 9999999ZZ

NERVS SYS, EYE, KIDNEY, LUNG & BRAIN DMG. OVEREXP TO

RTECS: 9999999ZZ

EFTS IN HUMANS & MAY AGGRAVATE PRE-EXISTING DISORDERS

RTECS: 9999999ZZ

TOLUENE MAY BE HARMFUL TO HUMAN FETUS BASED ON

RTECS: 9999999ZZ

INTENTIONAL ABUSE OF TOLUENE DURING PREGNANCY MAY

RTECS: 9999999ZZ

CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL.

RTECS: 9999999ZZ

INTO FRESH AIR. SEEK IMMED MED ATTN; KEEP WARM &

RTECS: 9999999ZZ

PROD CNTNS METHANOL WHICH

RTECS: 9999999ZZ

METABOLIZED TO FORMIC ACID & FORMALDEHYDE.

RTECS: 9999999ZZ

BLINDNESS. SINCE METABOLISM IS REQD FOR TOX SYMPS,

RTECS: 9999999ZZ

INGEST. ETHANOL COMPETES FOR SAME METABOLIC PATHWAY

RTECS: 9999999ZZ

ADMIN IS INDICATED IN SYMPTOMATIC PATIENTS/AT BLOOD

RTECS: 9999999ZZ

REMOVED BY HEMODIALYSIS.

RTECS: 9999999ZZ

COMPLETED. STOP SPILL @ SOURCE. PVNT FROM

RTECS: 9999999ZZ

SPREADING. IF RUNOFF OCCURS NOTIFY AUTHS AS REQD.

RTECS: 9999999ZZ

RECOVERY. ABSORB UNRECOVERABLE PROD. TRANSFER

RTECS: 9999999ZZ

RUN-OFF TO SEWERS/STREAMS/OTHER BODIES OF WATER. IF

RTECS: 9999999ZZ

INDUSTRIAL HYGIENIST). ENGINEERING/

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:EXPOS CAUSES IRRIT. SYMPS MAY INCL
STINGING, TEARING, REDNESS & SWELL. SKIN:EXPOS MAY CAUSE MILD
IRRIT. PRLNGD/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS,
BURNING, DRYING & CRACKING & SKIN BU RNS. INGEST:SINGLE DOSE ORAL
TOX IS LOW. SWALLOWING SM AMTS DURING NORM HNDLG IS NOT LIKELY TO
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: HARMFUL EFTS; SWALLOWING LG AMTS MAY
BE HARMFUL. MATL CAN ENTER LUNGS DURING SWALLOW/VOMIT & CAUSE LUNG
INFLAM &/OR DMG. INHAL:EXPOS TO VAP/MIST IS POSS. SYMPS OF EXPOS:
GI IRRIT (NAUS, VOMI T, DIARR), IRRIT (NOSE, THROAT, RESP TRACT),
CNS DEPRESS (DIZZ, DROW, WEAK, FATG, NAUS, HDCH, UNCON) & DEATH.
(SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS AND
PRE-EXISTING LUNG DISORDERS, EG ASTHMA-LIKE CONDITIONS, MAY BE
AGGRAVATED BY EXPOSURE TO THIS MATERIAL.

First Aid:EYES:IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
GENTLY W/WATER FOR AT LEAST 15 MIN WHILE HOLDING LIDS APART; SEEK
IMMED MED ATTN. SKIN:REMOVE CONTAMD CLTHG. WASH EXPOSED AREA W/SOAP
& WATER. I F SYMPS PERSIST, SEEK MED ATTN. LAUNDERCLTHG BEFORE
REUSE. INGEST:CALL MD/POIS CTL CTR IMMED FOR INSTRUCTIONS. MATL
CNTNS BOTH METHALON & PETRO DISTILS. ASPIR OF MATL INTO LUNGS DUE
TO VOMIT (ING 13)

Flash Point Method:TCC
Flash Point:38.0F,3.3C
Lower Limits:1.2%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE AND CARBON MONOXIDE,
VARIOUS HYDROCARBONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO PERSONAL PROTECTIVE EQUIPMENT SECTION OF MSDS.
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLAT & READILY GIVES OFF
VAPS WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY
PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, (SUPDAT)

Spill Release Procedures:SM SPILL:ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LG SPILL:ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FROM A REA OF SPILL UNTIL CLEAN-UP HAS BEEN (ING
21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN
EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR
SOLID), ALL HAZ PRECS GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS
INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED AND/OR
BONDED WHEN MATERIAL IS TRANSFERRED.

Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE
OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH RESPS (NEG
PRESS TYPE) UNDER SPECIFIED CNDTNS (CONSULT (ING 25)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESIST GLOVES SUCH AS NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: SMKNG, ELEC MOTORS, STATIC DISCHARGE OR OTHER IGNIT SOURCES
AT LOCATIONS DIST FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING
TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDU E)
CAN IGNITE EXPLO. EFTS OF OVEREXP: CHRONIC: TOLUENE APPEARS ON THE
NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK (ING 6)

Boiling Pt:B.P. Text:147F,64C
Vapor Pres:97.68 @68F
Vapor Density:>1
Spec Gravity:0.820
VOC Pounds/Gallon:813
Evaporation Rate & Reference:FASTER THAN ETHYL ETHER
Appearance and Odor:LIQUID.
Percent Volatiles by Volume:>99

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, OPEN FLAME AND PROLONGED
STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
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assume responsibility for the suitability of this information to their
particular situation.